Reductive Dimerization of Alkenes and Allenes Enabled by Photochemically Activated Zinc-Zinc Bonded Compounds.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c07390
Abstract: Metal radicals have shown versatile reactivity in modern synthetic chemistry. However, the use of zinc radicals for molecular synthesis has been barely explored. Here, we show that a transient zinc radical can be formed through… read more here.
Keywords: alkenes allenes; zinc zinc; dimerization alkenes; zinc ... See more keywords
Recent advances in zinc-zinc bonded complexes: synthesis and reactivity.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc02997j
Abstract: Since the seminal report on dizincocene [Zn2Cp*2] (Cp* = C5Me5) by Carmona and coworkers, zinc-zinc bonded complexes have garnered significant research interest owing to their structural versatility and applications in both stoichiometric and catalytic processes.… read more here.
Keywords: synthesis reactivity; zinc zinc; zinc bonded; bonded complexes ... See more keywords