Two novel zinc(II) coordination polymers constructed from in situ amidation ligands
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.12.100
Abstract: Abstract Two novel coordination compounds, [Zn(Hbimh) (H2O)]·H2O (1) and [Zn(Hbimh)]·(4,4ʹ-bpy)0.5 (2) (H3bimh = benzimidazole-5,6-hydrazide, 4,4ʹ-bpy = 4,4ʹ-bipyridine), have been prepared from the hydrothermal in situ amidation cyclization reactions of H3bimdc (H3bimdc = benzimidazole-5,6-dicarboxylic acid) and hydrazine hydrate (N2H4·H2O). Compound 1 exhibits… read more here.
Keywords: novel zinc; two novel; zinc coordination; situ amidation ... See more keywords
Six 1D/2D Zinc(II) coordination complexes constructed based on semirigid Bis(dimethylbenzimidazole) ligand and different carboxylates: Syntheses, structures, and photoluminescence properties
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.11.058
Abstract: Abstract A series of zinc(II) coordination complexes, formulated as {[Zn (dbim)1.5 (m-H2adica)]n·2H2O}n (1), [Zn (dbim) (H2adi)]n (2), [Zn (dbim) (m-H2bdc)]n (3), [Zn0.5 (dbim)0.5 (p-H2bdc)0.5]n (4), [Zn (dbim) (H2sdba)]n (5) and [Zn (dbim)0.5(H2atda)]n (6) (dbim = 1-(4-((2,5-dimethyl-3aH-benzo [d]imidazole-1… read more here.
Keywords: coordination complexes; dbim; zinc coordination; topology ... See more keywords
Constructions and properties of zinc coordination polymers based on 3,5-di(4H-1,2,4-triazol-4-yl) benzoic acid with different polycarboxylic acids as a secondary ligand
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DOI: 10.1016/j.poly.2016.12.043
Abstract: Abstract Five zinc coordination polymers, namely {[Zn(L)(NO 3 )]·(H 2 O)} n ( 1 ), {Zn 2 (L) 2 ( p -BDC)} n ( 2 ), {[Zn 2 (H 2 O) 2 (L)(1,3,5-BTC)]·H 2 O}… read more here.
Keywords: coordination; zinc coordination; acid; triazol benzoic ... See more keywords
Construction of five zinc coordination polymers with 4-substituted bis(trizole) and multicarboxylate ligands: Syntheses, structures and properties
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DOI: 10.1016/j.poly.2018.08.047
Abstract: Abstract Five zinc coordination polymers {[Zn2(mtrb)2(btec)]·H2O}n (1), {[Zn(mtrb)(Meip)]·H2O}n (2), [Zn(mtrb)(nip)]n (3), {[Zn(mtrb)(hip)]·H2O}n (4) and [Zn(mtrb)(nbdc)]n (5) (mtrb = 1,3-bis(1,2,4-triazol-4-ylmethyl)benzene, btec = 1,2,4,5-benzenetetracarboxylate, Meip = 5-methylisophthalate, nip = 5-nitroisophthalate, hip = 5-hydroxyisophthalate, nbdc = 4-nitro-1,2-benzenedicarboxylate) were synthesized and characterized. 1 shows a (4,4)-connected self-catenated 3D network with a… read more here.
Keywords: mtrb; coordination polymers; zinc coordination; five zinc ... See more keywords
Syntheses, crystal structures, and photocatalytic properties of two zinc(II) coordination polymers based on dicarboxylates and flexible bis(benzimidazole) ligands
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.04.011
Abstract: Abstract Two new ternary zinc(II) coordination polymers (CPs), catena-(μ2-phthalato)-(μ2-1,1′-hexane-1,6-diylbis(2-methyl-1H-benzimidazole))-zinc (CP 1) and catena-(μ2-phenylene-1,4-diacetato)-(μ2-1,1′-hexane-1,6-diylbis(1H-benzimidazole))-zinc (CP 2) were synthesized via hydrothermal process. CP 1 and CP 2 are named as [Zn(L1)(PA)]n and [Zn(L2)(PDA)]n (L1 = 1,1′-hexane-1,6-diylbis(2-methyl-1H-benzimidazole), L2 = 1,1′-hexane-1,6-diylbis(1H-benzimidazole), H2PA = phthalic acid,… read more here.
Keywords: photocatalytic properties; hexane diylbis; zinc coordination; coordination polymers ... See more keywords
A Zinc Coordination Complex Mimicking Carbonic Anhydrase for CO2 Hydrolysis and Sequestration.
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DOI: 10.1021/acs.inorgchem.9b01059
Abstract: Carbonic anhydrase (CA) mimicking is an effective and environmentally friendly strategy for carbon dioxide sequestration. Herein, we developed a nonanuclear CA-mimetic zinc coordination complex (1) which possesses a coordination environment similar to that of CA's… read more here.
Keywords: carbonic anhydrase; coordination; zinc coordination; zinc ... See more keywords
Synthesis and crystal structures of a copper(ii) dinuclear complex and zinc(ii) coordination polymers as materials for efficient oxidative desulfurization of dibenzothiophene
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DOI: 10.1039/c9nj01456j
Abstract: Dinuclear copper(ii) complex [Cu2(BAc)4(QX)2], and 2D zinc(ii) coordination polymer, [Zn(TDPA)2(TMPy)2]n, presented high oxidation and adsorption thermodynamics for dibenzothiophene sulfoxide (DBTO). read more here.
Keywords: synthesis crystal; crystal structures; zinc coordination; structures copper ... See more keywords
Distorted zinc coordination polyhedra in bis(1-ethoxy-2-{[(2-methoxyethyl)imino]methyl}propan-1-olato)zinc, a possible CVD precursor for zinc oxide thin films
Sign Up to like & getrecommendations! Published in 2022 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989022001475
Abstract: The coordination polyhedra of the zinc atoms in the title complex display long Zn—O bonds as parts of distorted trigonal bipyramids and octahedra. read more here.
Keywords: distorted zinc; coordination polyhedra; zinc coordination; zinc ... See more keywords