X-ray characterization, spectroscopic, DFT calculations and Hirshfeld surface analysis of two 3-D supramolecular mononuclear zinc(II) and trinuclear copper(II) complexes
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DOI: 10.1016/j.poly.2018.10.052
Abstract: Abstract Two three-dimensional mononuclear zinc(II) and trinuclear copper(II) complexes, [Zn(L2)2]·2CH3OH (1) and [Cu(L2)]3·CH3OH (2) (HL2 = 1-(2-{[(E)-3-bromo-5-chloro-2-hydroxybenzylidene]amino}phenyl)ethanone oxime), were synthesized via complexation of metal salts with based ligand HL1 (2-(3-bromo-5-chloro-2-hydroxyphenyl)-4-methyl-1,2-dihydroquinazoline 3-oxide, H is the deprotonatable hydrogen) originally.… read more here.
Keywords: trinuclear copper; copper complexes; zinc trinuclear; dft calculations ... See more keywords