A Zintl Cluster for Transition Metal-Free Catalysis: C=O Bond Reductions
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DOI: 10.1021/jacs.2c08559
Abstract: The first fully characterized boron-functionalized heptaphosphide Zintl cluster, [(BBN)P7]2– ([1]2–), is synthesized by dehydrocoupling [HP7]2–. Dehydrocoupling is a previously unprecedented reaction pathway to functionalize Zintl clusters. [Na(18-c-6)]2[1] was employed as a transition metal-free catalyst for… read more here.
Keywords: zintl cluster; catalysis; metal free; transition metal ... See more keywords
Electrochemically captured Zintl cluster-induced bismuthene for sodium-ion storage.
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DOI: 10.1039/d0cc08261a
Abstract: Bismuthene was prepared via the oxidation of Zintl clusters by electrochemical cathodic corrosion. It was found that the conversion of Zintl clusters from Bi22- to Bi2 occurred in the electrolyte having short alkyl chains due… read more here.
Keywords: induced bismuthene; zintl cluster; cluster induced; bismuthene sodium ... See more keywords
Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H2 and D2
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DOI: 10.1039/d2sc02552c
Abstract: Ligand exchange reactions of [Rh(COD){η4-Ge9(Hyp)3}] with L-type nucleophiles such as PMe3, PPh3, IMe4 (IMe4 = 1,3,4,5-tetramethylimidazol-2-ylidene) or [W(Cp)2H2] result in the displacement of the COD ligand to afford clusters with coordinatively unsaturated trigonal pyramidal rhodium(i)… read more here.
Keywords: supported low; exchange; zintl cluster; cluster supported ... See more keywords