From Three-Dimensional Clathrates to Two-Dimensional Zintl Phases AMSb2 (A = Rb, Cs; M = Ga, In) Composed of Pentagonal M-Sb Rings.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03217
Abstract: Three new antimonide Zintl phases, RbGaSb2, CsGaSb2, and CsInSb2, were discovered during exploration of corresponding A-M-Sb (A = Rb, Cs; M = Ga, In) ternary systems while searching for new clathrates. The AGaSb2 phases crystallize… read more here.
Keywords: three dimensional; zintl phases; dimensional clathrates; clathrates two ... See more keywords
Hydrides of Alkaline Earth-Tetrel (AeTt) Zintl Phases: Covalent Tt-H Bonds from Silicon to Tin.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b01944
Abstract: Zintl phases form hydrides either by incorporating hydride anions (interstitial hydrides) or by covalent bonding of H to the polyanion (polyanionic hydrides), which yields a variety of different compositions and bonding situations. Hydrides (deuterides) of… read more here.
Keywords: zintl phases; earth tetrel; hydrides alkaline; tetrel aett ... See more keywords
Exploiting the fraternal twin nature of thermoelectrics and topological insulators in Zintl phases as a tool for engineering new efficient thermoelectric generators
Sign Up to like & getrecommendations! Published in 2023 at "Journal of Materials Chemistry C"
DOI: 10.1039/d3tc00556a
Abstract: This review article presents a radical overview of the rich chemistry and physics of Zintl phases as it relates to their interesting structure-property relationships. In particular, it unveils the evolution... read more here.
Keywords: twin nature; zintl phases; chemistry; exploiting fraternal ... See more keywords
Special Issue: Advances in Zintl Phases
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DOI: 10.3390/ma12162554
Abstract: Zintl phases have garnered a great deal of attention for many applications. The term “Zintl phase” recognizes the contributions of the German chemist Eduard Zintl to the field of solid-state chemistry. While Zintl phases were… read more here.
Keywords: solid state; zintl phases; issue advances; chemistry ... See more keywords