Structure, Properties, and Reactivity of Polyoxocationic Zirconium and Hafnium Clusters: A Computational Investigation.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04142
Abstract: Tetravalent zirconium and hafnium molecular metal oxides clusters are key building blocks of many metal-organic frameworks; however, the chemical space to form all possible MOF nodes is vast, containing many potential new clusters. Our computational… read more here.
Keywords: zirconium hafnium; clusters computational; zirconium; structure properties ... See more keywords
Catalytic Zirconium/Hafnium-Based Metal–Organic Frameworks
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DOI: 10.1021/acscatal.6b02923
Abstract: Metal–organic frameworks (MOFs) are highly versatile materials that find applications in several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and nowadays represent a rapidly growing family. Their unique and intriguing properties make them privileged… read more here.
Keywords: hafnium based; metal organic; zirconium; organic frameworks ... See more keywords
Benzylene-linked [PNP] scaffolds and their cyclometalated zirconium and hafnium complexes.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt00413c
Abstract: The benzylene-linked [PNP] scaffolds HN(CH2-o-C6H4PPh2)2 ([A]H) and HN(C6H4-o-CH2PPh2)2 ([B]H) have been used for the synthesis of zirconium and hafnium complexes. For both ligands, the dimethylamides [A]M(NMe2)3 ([A]1-M) and [B]M(NMe2)3 ([B]1-M) were prepared and converted to… read more here.
Keywords: benzylene linked; pnp scaffolds; zirconium; linked pnp ... See more keywords
Fast and scalable synthesis of uniform zirconium-, hafnium-based metal-organic framework nanocrystals.
Sign Up to like & getrecommendations! Published in 2017 at "Nanoscale"
DOI: 10.1039/c7nr06274e
Abstract: Metal-organic frameworks based on zirconium or hafnium possess tantalizing commercial prospects due to their high stability but require a long reaction time to form crystals. The fast synthesis of uniform Zr-, Hf-MOF nanocrystals at scale… read more here.
Keywords: fast uio; metal organic; metal; uio fast ... See more keywords