Core design of ma-transmutation fast reactor with zirconium hydride target
Sign Up to like & getrecommendations! Published in 2021 at "Nuclear Engineering and Design"
DOI: 10.1016/j.nucengdes.2021.111254
Abstract: Abstract The use of zirconium hydride in fast reactors provides excellent MA transmutation performance by neutron moderation with hydrogen. This study has designed an MA transmutation fast reactor loading a ‘target” containing MA-zirconium hydride in… read more here.
Keywords: zirconium hydride; core; transmutation; target ... See more keywords
Zirconium-hydride-catalyzed site-selective hydroboration of amides for the synthesis of amines: Mechanism, scope, and application
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Journal of Catalysis"
DOI: 10.1016/s1872-2067(21)63853-6
Abstract: Abstract Developing mild and efficient catalytic methods for the selective synthesis of amines is a longstanding research objective. In this respect, catalytic deoxygenative amide reduction has proven to be promising but challenging, as this approach… read more here.
Keywords: zirconium hydride; bond cleavage; hydride catalyzed; selective hydroboration ... See more keywords
Isolable zirconium hydride species in the reaction of amido complexes with amine-boranes.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt00857k
Abstract: Mono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η5-C5Me5)(NMe2)nCl3-n] (n = 3, 1) with amine-borane adducts NHR2BH3 (R2 = Me2, HtBu). The reactions involve the formation of… read more here.
Keywords: zirconium hydride; hydride species; amido complexes;
Hydrogen Permeation Behavior of Zirconium Nitride Film on Zirconium Hydride
Sign Up to like & getrecommendations! Published in 2022 at "Materials"
DOI: 10.3390/ma15020550
Abstract: Hydrogen permeation barrier plays an important role in reducing hydrogen loss from zirconium hydride matrix when used as neutron moderator. Here, a composite nitride film was prepared on zirconium hydride by in situ reaction method… read more here.
Keywords: nitride film; zirconium hydride; film; hydrogen permeation ... See more keywords
Mechanisms of Growth and Hydrogen Permeation of Zirconium Nitride Film on Zirconium Hydride
Sign Up to like & getrecommendations! Published in 2022 at "Materials"
DOI: 10.3390/ma16010349
Abstract: Nitride film as a hydrogen permeation barrier on zirconium hydride has seldom been studied. In this work, the zirconium nitride films were prepared on zirconium hydride in an atmosphere of N2 and N2 + H2… read more here.
Keywords: hydrogen permeation; film; zirconium hydride; zirconium ... See more keywords