Homo/Heteropentanuclear Porphyrazine MgII, ZnII, and PdII Macrocycles with Externally Pending PdCl2 and Pd(CBT)2 Units: Synthesis, Physicochemical Characterization, and Photoactivity Studies.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c01195
Abstract: Recent work has been developed on two new classes of neutral porphyrazine complexes of formulas [(PdCl2)4Py8PzM]·xH2O (Py8Pz = octakis(2-pyridyl)porphyrazinato anion; M = MgII(H2O), ZnII, PdII) and [{Pd(CBT)2}4Py8PzM]·xH2O (M = MgII(H2O), ZnII; CBT = m-carborane-1-thiolate anion).… read more here.
Keywords: porphyrazine; mgii; znii; znii pdii ... See more keywords
Transmetalation for Flexible Pendant-Armed Schiff-Base Macrocyclic Complexes Influenced by Halide Effects.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b02835
Abstract: Three 46-membered [2 + 2] pendant-armed Schiff-base macrocyclic dinuclear CdII and CuII complexes (2a, 2b, and 3b) and one 23-membered [1 + 1] CuII macrocycle 4a were prepared from the template-directed condensation reactions between 1,2-bis(2-aminoethoxy)-ethane… read more here.
Keywords: transmetalation; znii; macrocyclic complexes; cdii ... See more keywords
A macrocyclic tetranuclear ZnII complex as a receptor for selective dual fluorescence sensing of F− and AcO−: effect of a macrocyclic ligand
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj03481a
Abstract: Fluorimetric detection of F−/AcO− with an additional ‘INHIBIT’ logic gate response for F−/H+ and AcO−/H+ in an aqueous-methanol medium by a 48-membered macrocyclic ZnII-complex DAS has been explored by combined experimental and theoretical study. read more here.
Keywords: complex receptor; znii; macrocyclic tetranuclear; receptor selective ... See more keywords
Au → M bonds promote catalytic alkyne hydrofunctionalisation.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01008b
Abstract: The impact of metalloligands on Au catalysed alkyne hydrofunctionalisation is studied. Ambiphilic PMP-type ligands (M = CuI, AgI, ZnII) stabilise Au → M bonds including unprecedented AuI → ZnII interactions. The Lewis acidity of Au… read more here.
Keywords: alkyne hydrofunctionalisation; znii; promote catalytic; hydrofunctionalisation ... See more keywords
Synthesis and characterization of heterobimetallic SnIV–CuII/ZnII complexes: DFT studies, cleavage potential and cytotoxic activity
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Biomolecular Structure and Dynamics"
DOI: 10.1080/07391102.2019.1596837
Abstract: Abstract Heterobimetallic complexes [Cu(L)Sn(CH3)2(H2O)(Cl)] (3) and [Zn(L)Sn(CH3)2(H2O)(Cl)] (4) have been synthesized from their monometallic analogs [Cu(L)(H2O)(Cl)] (1) and [Zn(L)(H2O)(Cl)] (2) of Schiff base ligand (L) which were characterized by various spectroscopic and analytical methods. DFT… read more here.
Keywords: dna; znii; characterization heterobimetallic; activity ... See more keywords