Post-synthetic modification of zirconium metal-organic frameworks by catalyst-free aza-Michael additions.
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DOI: 10.1039/c8dt03312a
Abstract: The reactions of the zirconium MOF [Zr6O4(OH)4(bdc-NH2)6] (UiO-66-NH2, bdc-NH2 = 2-amino-1,4-benzenedicarboxylate) with the Michael acceptors acrylonitrile (CH2[double bond, length as m-dash]CHCN), acrylic acid (CH2[double bond, length as m-dash]CHCO2H), methyl acrylate (CH2[double bond, length as m-dash]CHCO2Me)… read more here.
Keywords: zr6o4 bdc; bond; ch2 double; bdc ... See more keywords