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Crystal structures of two PCN pincer iridium complexes and one PCP pincer carbodiphosphorane iridium intermediate: substitution of one phosphine moiety of a carbodiphosphorane by an organic azide

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The syntheses and crystal structures of two PCN pincer iridium complexes, prepared from the reaction of their respective PCP pincer carbodiphosphorane iridium precursors with an organic azide, are reported. Crystal… Click to show full abstract

The syntheses and crystal structures of two PCN pincer iridium complexes, prepared from the reaction of their respective PCP pincer carbodiphosphorane iridium precursors with an organic azide, are reported. Crystal data for one of the precursors is also discussed.

Keywords: crystal structures; carbodiphosphorane; structures two; two pcn; pincer; iridium

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019

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