Base-Promoted Radical Azofluoromethylation of Unactivated Alkenes.
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DOI: 10.1021/acs.orglett.0c01395
Abstract: The base-induced reaction of aryl diazonium salts with commercially available CF3SO2Na/CF2HSO2Na allows for the generation of the corresponding diazene radicals along with fluoromethyl radicals. The addition of fluoromethyl radicals to alkenes with subsequent diazene trapping… read more here.
Keywords: promoted radical; azofluoromethylation unactivated; azofluoromethylation; unactivated alkenes ... See more keywords