A BF3‐Doped MXene Dual‐Layer Interphase for a Reliable Lithium‐Metal Anode
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202210111
Abstract: A dual‐layer interphase that consists of an in‐situ‐formed lithium carboxylate organic layer and a thin BF3‐doped monolayer Ti3C2 MXene on Li metal is reported. The honeycomb‐structured organic layer increases the wetting of electrolyte, leading to… read more here.
Keywords: metal anode; dual layer; bf3; layer ... See more keywords
Boron trifluoride interaction studies on graphdiyne nanotubes – A first-principles insight
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2019.136841
Abstract: Abstract We investigated the adsorption of boron trifluoride (BF3) gas molecules on graphdiyne nanotube (G2YNT) based on first-principles studies. We ensured the stability of G2YNT using cohesive energy and found stable. G2YNT shows semiconductor properties.… read more here.
Keywords: boron trifluoride; bf3; trifluoride interaction; g2ynt ... See more keywords
Synthesis and electrochemical properties of self-doped solid polymer electrolyte based on lithium 4-styrene sulfonate with BF3-THF
Sign Up to like & getrecommendations! Published in 2021 at "Solid State Ionics"
DOI: 10.1016/j.ssi.2021.115563
Abstract: Abstract Poly(lithium 4-styrene sulfonate)-based self-doped solid polymer electrolytes were prepared by radical polymerization and ion-exchange reactions of sodium 4-styrene sulfonate and oligo(ethylene oxide) methyl ether methacrylate. The crystalline melting temperature of ethylene oxide was reduced… read more here.
Keywords: bf3 thf; styrene sulfonate; lithium; bf3 ... See more keywords
Significantly increased stability of donor-acceptor molecular complexes under heterogeneous conditions: Synthesis, characterization and photosensitizing activity of a nano-structured porphyrin-Lewis acid adduct.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c13598
Abstract: While the BF3 complexes of meso-tetra(aryl)porphyrins are readily decomposed into their components under aqueous conditions, immobilization of meso-tetrakis(N-methylpyridinium-4-yl)porphyrin (H2TMPyP) on a nanosized polymer (sodium salt of amberlyst 15, nanoAmbSO3Na) formed a water stable BF3 complex… read more here.
Keywords: bf3; nanoambso3 h2tmpyp; molecular complexes; spectroscopy ... See more keywords
C(sp3)-H Ritter amination by excitation of in situ generated iodine(III)-BF3 complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03283j
Abstract: Visible light excitation of iodine(III)-BF3 complex enables the formation of carbocations from C(sp3)-H bonds. The complexes are generated catalytically from iodoarene, carboxylate ligand, the oxidizing agent Selectfluor, and the Lewis acid BF3. This modular catalytic… read more here.
Keywords: excitation; bf3; sp3 ritter; iodine iii ... See more keywords