Articles with "catalyst surface" as a keyword



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Bioinspired Electrode for the Production and Timely Separation of Nitrile and Hydrogen.

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Published in 2023 at "Small"

DOI: 10.1002/smll.202208044

Abstract: Replacing electrocatalytic oxygen evolution reaction (OER) with amine oxidation reaction is adopted to boost clean and environment-friendly energy source hydrogen (H2 ) in water. However, the electrocatalytic reaction is severely restricted by the strong adsorption… read more here.

Keywords: timely separation; catalyst surface; hydrogen; production timely ... See more keywords
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Ionic Liquid Dispersed Ti/SBA-15 for Double-Bond Cleavage Oxidation of α-Methylstyrene into Acetophenone

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Published in 2019 at "Catalysis Letters"

DOI: 10.1007/s10562-019-02911-7

Abstract: A composite material Ti/SIL was prepared by Ti(OC4H9)4 coordinating to imidazolium ionic liquid grafted on SBA-15 and characterized by FT-IR, XRD, TEM, XPS, NH3-TPD and N2 adsorption–desorption technique. The catalytic performance of the prepared Ti/SIL… read more here.

Keywords: ionic liquid; liquid; cleavage; oxidation methylstyrene ... See more keywords
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Engineering Catalyst-Electrolyte Microenvironments to Optimize the Activity and Selectivity for the Electrochemical Reduction of CO2 on Cu and Ag.

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Published in 2022 at "Accounts of chemical research"

DOI: 10.1021/acs.accounts.1c00650

Abstract: ConspectusThe electrochemical reduction of carbon dioxide (CO2R) driven by renewably generated electricity (e.g., solar and wind) offers a promising means for reusing the CO2 released during the production of cement, steel, and aluminum as well… read more here.

Keywords: catalyst; catalyst surface; selectivity; electrochemical reduction ... See more keywords
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An APXPS Probe of Cu/Pd Bimetallic Catalyst Surface Chemistry of CO2 Toward CO in the Presence of H2O and H2

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Published in 2020 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.0c04717

Abstract: The electroreduction of CO2 represents a promising avenue to convert greenhouse gas into valuable fuels and store energy from intermittent renewable sources. Cu-based bimetallic surfaces constitute... read more here.

Keywords: chemistry; probe bimetallic; apxps probe; surface chemistry ... See more keywords
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Origin of the drastic current decay during potentiostatic alkaline methanol oxidation.

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Published in 2020 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.0c06547

Abstract: The current production from the alkaline methanol electrooxidation reaction does not reach a steady-state on a smooth platinum catalyst under potentiostatic conditions. We investigated two possible explanations for this phenomenon: changes on the catalyst surface… read more here.

Keywords: alkaline methanol; oxidation; spectroscopy; catalyst surface ... See more keywords
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Distinguishing homogeneous advanced oxidation processes in bulk water from heterogeneous surface reactions in organic oxidation

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Published in 2023 at "Proceedings of the National Academy of Sciences of the United States of America"

DOI: 10.1073/pnas.2302407120

Abstract: Significance Heterogeneous catalytic oxidation technologies for water purification, such as Fenton and Fenton-like catalytic oxidation, involve intricate interfacial reactions at the solid catalyst surface and in bulk solution. To date, the difference in the reaction… read more here.

Keywords: oxidation; catalyst surface; surface; bulk water ... See more keywords