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Published in 2017 at "Journal of Molecular Modeling"
DOI: 10.1007/s00894-017-3230-2
Abstract: AbstractThe dual role of the ionic liquid 1-butyl-3-methyl-imidazolium trifluoroacetic acid ([C4mim]TFA) as an extractant for thiophene (TH) and a catalyst for the oxidation of TH was explored at the molecular level by performing density functional…
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Keywords:
c4mim;
ionic liquid;
c4mim tfa;
oxidative desulfurization ... See more keywords
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Published in 2020 at "Journal of Sol-Gel Science and Technology"
DOI: 10.1007/s10971-020-05332-w
Abstract: MoOx/Al2O3 based catalyst has long been widely used as an active catalyst in Oxidative Desulfurization reaction due to its high stability under severe reaction conditions and high resistance to sulfur poisoning. In this context, 4…
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Keywords:
moo3;
al2o3;
method;
catalyst ... See more keywords
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Published in 2020 at "Journal of Nanoparticle Research"
DOI: 10.1007/s11051-020-04847-1
Abstract: Three-dimensional ordered (3DOM) H3PW12O40/TiO2 nanocomposites with anatase TiO2 exposed {001} facets are fabricated by HF treatment and applied as effective catalyst in oxidative desulfurization (ODS) process. The structure characterization results including SEM, TEM, XRD, N2…
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Keywords:
tio2;
h3pw12o40 tio2;
3dom h3pw12o40;
oxidative desulfurization ... See more keywords
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Published in 2020 at "Reaction Kinetics, Mechanisms and Catalysis"
DOI: 10.1007/s11144-020-01852-2
Abstract: Using wet impregnation method, MoO3 particles were loaded on hierarchical silica support, SBA-15, and applied for oxidative desulfurization (ODS) process from a model oil containing dibenzothiophene (DBT). The experiments were carried out by the use…
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Keywords:
model oil;
spectroscopy;
oxidative desulfurization;
oil ... See more keywords
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Published in 2018 at "Petroleum Science"
DOI: 10.1007/s12182-018-0272-8
Abstract: Three amphiphilic peroxophosphomolybdates [C4mim]3PMo4O24, [C8mim]3PMo4O24 and [C16mim]3PMo4O24 were synthesized and characterized. These catalysts were used for extraction and catalytic oxidative desulfurization of fuel with H2O2 as an oxidant and ionic liquid [C4mim]BF4 as an extractant.…
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Keywords:
desulfurization;
ionic liquid;
amphiphilic peroxophosphomolybdates;
peroxophosphomolybdates oxidative ... See more keywords
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Published in 2018 at "Applied Catalysis B: Environmental"
DOI: 10.1016/j.apcatb.2018.03.005
Abstract: Abstract Keggin-type polyoxometalates (POM) immobilized on alkylaminophosphazene (RPN)-functionalized silica (POM/RPN-SiO2) are new effective single-site solid catalysts for oxidative desulfurization (ODS) of diesel fuel under mild conditions in a biphasic system composed of a benzothiophene-containing model…
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Keywords:
diesel fuel;
functionalized silica;
pom;
diesel ... See more keywords
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Published in 2018 at "Applied Catalysis B: Environmental"
DOI: 10.1016/j.apcatb.2018.07.037
Abstract: Abstract Electronic structure of active sites plays a crucial role in redox catalysts. Herein, graphitic carbon nitride (g-C3N4) decorated with metallic MoO2 heterojunction nanocomposites were successfully synthesized through a facile calcination route. XPS, UPS, UV–vis…
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Keywords:
electronic structure;
oxidative desulfurization;
c3n4;
heterojunction ... See more keywords
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Published in 2017 at "Applied Thermal Engineering"
DOI: 10.1016/j.applthermaleng.2016.10.015
Abstract: Abstract In the present work, ultrasound assisted oxidative desulfurization (UAOD) of gas oil as the feedstock with sulfur content of 2210 ppmw was investigated using a mixture of hydrogen peroxide and formic acid as the oxidant…
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Keywords:
molar ratio;
gas;
process;
gas oil ... See more keywords
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Published in 2019 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2019.04.156
Abstract: Abstract In this work, reduced graphene oxide (rGO) with homogeneously dispersed phosphotungstate acid (HPW), were directly fabricated by using electrochemical strategy. In this one-pot route, the reduction of graphene oxide (GO) and HPW anchoring on…
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Keywords:
oxidative desulfurization;
hpw;
high efficient;
rgo ... See more keywords
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Published in 2019 at "Advanced Powder Technology"
DOI: 10.1016/j.apt.2019.09.030
Abstract: Abstract In this manuscript, the catalytic oxidative desulfurization (CODS) was proceeded using PMoV@CuO@PAN hybrid nanocatalyst. The nanocatalyst was prepared by the composition of potassium salt of 11-molybdo-1-vanadophosphat (PMoV), copper oxide (CuO), and polyaniline (PAN). The…
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Keywords:
desulfurization;
fuel;
reaction;
oxidative desulfurization ... See more keywords
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Published in 2020 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2020.105926
Abstract: Abstract In this work, the effect of microwave irradiation on the catalytic oxidative desulfurization (ODS) of light gasoil fraction has been investigated using core/shell magnetic silica supported with phosphotungstic acid (Ni@SiO2\PWA) nanocomposite catalyst. Different experimental…
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Keywords:
catalytic oxidative;
desulfurization;
gasoil;
sio2 pwa ... See more keywords